Defect Mediated Small Molecular Doping of Graphene

TitleDefect Mediated Small Molecular Doping of Graphene
Publication TypeJournal Article
Year of Publication2021
AuthorsS, R, Dutta, S, Ray, D
JournalAdvanced Optical Materials
Volumen/a
Issuen/a
Pagination2002046
Date Published2021/02/02
ISBN Number2195-1071
Keywordsdefects, DFT calculations, doping, fluorination, graphene, small-molecule dopants
Abstract

Abstract It is shown that the improved electrical properties of graphene on organic small-molecule-based surface doping is dominated by the doping effect of these materials at the defect sites on graphene. It is hypothesized that this may be due to the healing effect of semi-bulk substitution-like doping at the defect sites. In this study, defects are intentionally created with varying densities on graphene by exposing it to trifluoro methane (CHF3) plasma for different time periods. The films are then doped by solution spin coating of bis(trifluoromethane)sulfonamide (TFSA). The measured change in electrical conductivity is proportional to the defect density of the graphene, implying a healing effect of these organic small molecular dopants. First principles calculations are performed to capture this mechanism, and the results conform with the experimental observations. The introduction of defects leads to a modulation of the workfunction while adversely affecting the charge carrier transport properties. It is shown that subsequent TFSA doping aids in healing the defective sites thereby improving conduction while maintaining the changed workfunction. The two processes act in tandem for the enhanced electrical properties of graphene.

URLhttps://doi.org/10.1002/adom.202002046
Short TitleAdvanced Optical Materials